Search In this Thesis
   Search In this Thesis  
العنوان
Relaxation phenomena studies on some polymers and polymer blends /
المؤلف
Mohammed, Alaa El­din El­kotp Abd El­kader.
هيئة الاعداد
باحث / علاء الدين القطب عبدالقادر محمد
مشرف / مصطفى دياب مجاهد
مشرف / كريستوف شيك
مشرف / مصطفى توفيق
الموضوع
Relaxation Phenomena.
تاريخ النشر
2002.
عدد الصفحات
274 p. :
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
الفيزياء والفلك (المتنوعة)
تاريخ الإجازة
01/01/2002
مكان الإجازة
جامعة المنصورة - كلية العلوم - Department of physics
الفهرس
Only 14 pages are availabe for public view

from 314

from 314

Abstract

This thesis aims to study relaxation processes in the Semi­crystalline polymers. The thesis was carried out using three techniques; Differential Scanning Calorimetry (DSC), Temperature Modulated Scanning Calorimetry (TMDSC) and Dielectric Spectroscopy (DS). Using the TMDSC the results of the thesis revealed that: the Semi­crystalline polymers are consists of three fractions; the rigid crystalline fraction (RCF), the rigid amorphous fraction (RAF) and the mobile amorphous fraction (MAF). The thesis revealed that the relaxation processes found in these polymers are of different kinds, these processes are the glass transition relaxation which occur at the glass transition temperature, the crystallization structure relaxation which occur at the crystallization temperature, the rigid amorphous fraction relaxation which occur above the glass transition temperature and the reversing melting relaxation which occur when the semi­crystalline crystallized at high crystallization temperature. Beside these relaxations the dielectric relaxations where investigated using the DS. The Dielectric results were analyzed using the Havriliak Negami model.