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العنوان
Synergetic Adsorption and Photocatalytic Activity of Tungsten Trioxide Immobilized Graphene oxide for Removal of Organic and Inorganic Water Pollutants /
المؤلف
Eissa, Amal Abd El-Hakim Taha.
هيئة الاعداد
باحث / Amal Abd El-Hakim Taha Eissa
مشرف / Maged Abd El Tawab El Kemary
مشرف / Ibrahim Mahmoud El-Mehasseb
مشرف / Hamdy El-Sheshtawy
مناقش / Maged Abd El Tawab El Kemary
الموضوع
Chemistry.
تاريخ النشر
2022.
عدد الصفحات
118 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Chemistry (miscellaneous)
تاريخ الإجازة
22/2/2022
مكان الإجازة
جامعة كفر الشيخ - كلية العلوم - Biochemistry
الفهرس
Only 14 pages are availabe for public view

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from 112

Abstract

This thesis contain data and information about Synergism between adsorption and photocatalytic activity in heterocatalysis improve the overall performance of organic and inorganic pollutants removal. We report the WO3/GO composite immobilized on chitosan to enhance the adsorption process and decorated with Ag NPs for efficient photocatalytic visible light absorption. The ternary photocatalyst (x%Ag/WO3/GO (x= 0, 1, and 3) was characterized by SEM, TEM, XRD, FTIR, XRD, and UV-Vis techniques. The obtained results show that both GO sheets and Cs enhanced the adsorption process, while Ag NPs enhance the photocatalytic performance of WO3/GO composite. As expected, the 3%Ag/WO3/GO shows excellent catalytic and photocatalytic performance of the removal of organic (methylene blue, and p-nitrophenol) and inorganic (Cr6+) water pollutants. 3%Ag/WO3/GO composite removes 98 % of MB (20 min) in absence of light, where more than 98% of MB (8 min) and 95% of p-nitrophenol (8 min) were removed after visible light irradiation. Enhanced adsorption of MB and Cr6+ was attributed to π-π stacking and electrostatic attractive potential over the catalyst, respectively. Based on the experimental results and trapping experiments, the charge separation through the Z-scheme WO3/GO facilitate the charge migration and boost the photocatalyst performance. The photocatalytic activity WO3/GO was increased by the surface decorated plasmonic Ag NPs. The free surface plasmonic electrons in Ag NPs were injected to the GO CB to induce the reactive superoxide radicals. The ternary photocatalyst Ag/WO3/GO was stable and reusable which is beneficial for removal of water pollutants.